Direct Grafting of Free‐Base meso‐Triarylporphyrins on Electrode Materials through Diazonium Reduction: Reversible Zinc(II) Metallation of the Resulting Materials. Issue 1 (28th October 2015)

• Record Type: Journal Article
• Authors: Hebié, Seydou; Devillers, Charles H.; Fournier, Sophie; Lucas, Dominique
• Is Part Of: ChemElectroChem. Volume 3:Issue 1(2016)
• Page Start: 45
• Page End: 50
• Publication Date: 2015-10-28
• Subjects: diazonium electroreduction -- molecular electrochemistry -- porphyrinoids -- surface chemistry -- thin films; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.201500433
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract: Electroreduction of free base meso ‐diazonium‐triarylporphyrins, generated in situ from their corresponding meso ‐aminotriarylporphyrin precursors, leads to the formation of a covalently grafted porphyrin film. In this new material, contrary to recently published results, the free base porphyrin core is directly bonded to the surface, that is, without any spacer such as phenyl fragments. These thin films are characterized by cyclic voltammetry (CV), UV/Vis absorption spectroscopy and water angle contact. The electrochemical response is in agreement with a multilayer structure. Efficient and reversible zinc metallation of the immobilized porphyrin units is readily achieved opening the door to numerous applications in sensing and electrocatalysis. Abstract : French connection : Electroreduction of free base meso ‐diazonium‐triarylporphyrins leads to the formation of a directly (i.e. without any spacer) and covalently grafted porphyrin film on GC, ITO and Pt electrodes (see picture). This new material is characterized by using cyclic voltammetry, UV/Vis absorption spectroscopy, and water angle contact measurements. Efficient and reversible zinc metallation of the porphyrin units is also demonstrated.