Cover Picture: Solid‐State Molecular Nanomagnet Inclusion into a Magnetic Metal–Organic Framework: Interplay of the Magnetic Properties (Chem. Eur. J. 2/2016). Issue 2 (3rd December 2015)

• Record Type: Journal Article
• Authors: Mon, Marta; Pascual‐Álvarez, Alejandro; Grancha, Thais; Cano, Joan; Ferrando‐Soria, Jesús; Lloret, Francesc; Gascon, Jorge; Pasán, Jorge; Armentano, Donatella; Pardo, Emilio
• Is Part Of: Chemistry. Volume 22:Issue 2(2016)
• Page Start: 437
• Page End: 437
• Publication Date: 2015-12-03
• Subjects: magnetic ordering -- metal–organic frameworks -- multifunctional materials -- quantum tunneling effects -- single‐ion magnet; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201504562
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Solid‐state incorporation of a single‐ion magnet (SIM) within the pores of a magnetic 3D metal–organic framework (MOF) in a single‐crystal to single‐crystal process has been demonstrated. The resulting host–guest supramolecular aggregate affords the first deep study on the interplay of the internal magnetic field of the MOF and the slow magnetic relaxation of the SIM allowing the observation of a partial suppression of the quantum‐tunneling effects operative in the SIM. More information can be found in the Full Paper by D. Armentano, E. Pardo et al. onpage 539 ff.