Microporous Polymers from a Carbazole‐Based Triptycene Monomer: Synthesis and Their Applications for Gas Uptake. Issue 2 (26th November 2015)

• Record Type: Journal Article
• Authors: Zhai, Tian‐Long; Tan, Liangxiao; Luo, Yi; Liu, Jun‐Min; Tan, Bien; Yang, Xiang‐Liang; Xu, Hui‐Bi; Zhang, Chun
• Is Part Of: Chemistry, an Asian journal. Volume 11:Issue 2(2016)
• Page Start: 294
• Page End: 298
• Publication Date: 2015-11-26
• Subjects: gas adsorption -- microporous materials -- polymers -- synthesis -- triptycene; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201501105
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: Two kinds of novel organic microporous polymersTCP s (TCP‐A andTCP‐B ) were prepared by two cost‐effective synthetic strategies from the monomer of tricarbazolyltriptycene (TCT ). Their structure and properties were characterized by FT‐IR, solid 13 C NMR, powder XRD, SEM, TEM, and gas absorption measurements.TCP‐B displayed a high surface area (1469 m 2 g −1 ) and excellent H2 storage (1.70 wt % at 1 bar/77 K) and CO2 uptake abilities (16.1 wt % at 1 bar/273 K), which makes it a promising material for potential application in gas storage. Abstract : High surf is present : Two organic microporous polymers (TCP‐A andTCP‐B ) were prepared by two cost‐effective synthetic strategies from the monomer of tricarbazolyltriptycene (TCT ).TCP‐B displayed a high surface area and excellent H2 storage and CO2 uptake abilities.