3D Graphene‐Infused Polyimide with Enhanced Electrothermal Performance for Long‐Term Flexible Space Applications. Issue 48 (19th October 2015)

• Record Type: Journal Article
• Authors: Loeblein, Manuela; Bolker, Asaf; Tsang, Siu Hon; Atar, Nurit; Uzan‐Saguy, Cecile; Verker, Ronen; Gouzman, Irina; Grossman, Eitan; Teo, Edwin Hang Tong
• Is Part Of: Small. Volume 11:Issue 48(2015)
• Page Start: 6425
• Page End: 6434
• Publication Date: 2015-10-19
• Subjects: 3D graphene -- ageing -- flexible electronics -- polyimide -- space environment simulation; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201502670
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract : Polyimides (PIs) have been praised for their high thermal stability, high modulus of elasticity and tensile strength, ease of fabrication, and moldability. They are currently the standard choice for both substrates for flexible electronics and space shielding, as they render high temperature and UV stability and toughness. However, their poor thermal conductivity and completely electrically insulating characteristics have caused other limitations, such as thermal management challenges for flexible high‐power electronics and spacecraft electrostatic charging. In order to target these issues, a hybrid of PI with 3D‐graphene (3D‐C), 3D‐C/PI, is developed here. This composite renders extraordinary enhancements of thermal conductivity (one order of magnitude) and electrical conductivity (10 orders of magnitude). It withstands and keeps a stable performance throughout various bending and thermal cycles, as well as the oxidative and aggressive environment of ground‐based, simulated space environments. This makes this new hybrid film a suitable material for flexible space applications. Abstract : A polyimide (PI)–3D‐graphene (3D‐C) hybrid, 3D‐C/PI, is developed which renders extraordinary enhancements of thermal conductivity (one order‐of‐magnitude) and electrical conductivity (10 orders‐of‐magnitude), and withstands and keeps a stable performance throughout various bending and thermal cycles, as well as the oxidative and aggressive environment of ground‐based simulated space environment.