ChemInform Abstract: Platinum‐Catalyzed Cascade Rearrangement Reaction of 1, 5‐Diynyl Esters: Unusual Regioselective 1, 5‐Hydride Migration. Issue 52 (10th December 2015)

• Record Type: Journal Article
• Authors: Zhu, Hui; Huang, Jiapian; Fan, Congbin; Chen, Zhiyuan
• Is Part Of: ChemInform. Volume 46:Issue 52(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-12-10
• Subjects: indan derivatives -- ring closure reactions, annulation reactions -- rearrangements -- cascade reactions, domino reactions, tandem reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201552087
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Diynes of type (I), (III), and (V) are found to undergo a PtCl2 ‐catalyzed highly regioselective 1, 3‐acyloxy migration/pentannulation/1.5‐hydride shift process resulting in the formation of (E)‐2‐vinyl‐3‐oxo‐1‐methyleneindenes.