An improved synthesis of [26‐2H3]castasterone. (2nd November 2015)

• Record Type: Journal Article
• Authors: Zhabinskii, Vladimir N.; Gulyakevich, Olga V.; Kurman, Peter V.; Shabunya, Polina S.; Fatykhava, Svetlana A.; Khripach, Vladimir A.
• Is Part Of: Journal of labelled compounds & radiopharmaceuticals. Volume 58:Number 13/14(2015)
• Page Start: 469
• Page End: 472
• Publication Date: 2015-11-02
• Subjects: brassinosteroids -- epicastasterone -- castasterone -- synthesis -- deuterium; Tracers (Chemistry) -- Periodicals; Radiopharmaceuticals -- Periodicals; 615.8424
• DOI: 10.1002/jlcr.3353
• Languages: English
• ISSNs: 0362-4803

Abstract

Abstract : Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐ 2 H3 ]castasterone. The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids. Abstract : Commercially available epicastasterone has been employed as a starting material for the preparation of [26‐ 2 H3 ]castasterone1 . The chemical synthesis has been realized in 13 chemical steps and 4.6% total yield. The target compound is intended to be used as internal standard for the quantitative analysis of brassinosteroids.