О, О‐Dialkyl‐S‐(1, 1‐dimethyl‐2‐oxoethyl)dithiophosphates: Synthesis and Reactions with n‐Nucleophiles. Issue 6 (30th June 2015)

• Record Type: Journal Article
• Authors: Gazizov, Mukattis B.; Khairullin, Rafail A.; Aksenov, Nikita G.; Sinyashin, Oleg G.
• Is Part Of: Heteroatom chemistry. Volume 26:Issue 6(2015)
• Page Start: 436
• Page End: 440
• Publication Date: 2015-06-30
• Subjects: Heterocyclic chemistry -- Periodicals; 547.59
• DOI: 10.1002/hc.21278
• Languages: English
• ISSNs: 1042-7163

Abstract

ABSTRACT: Hydrolysis of the new types of iminium salts was used to synthesize О, О ‐dialkyl‐ S ‐(1, 1‐dimethyl‐2‐oxoethyl)dithiophosphates or 2‐dialkoxythiophosphorylthio‐substituted aldehydes with carbon isochain. Reactions of aldehydes with N‐, N, N‐, and O, N‐nucleophiles gave new phosphorylated imines containing an acetal group at different positions, perhydro‐1, 3‐diazol and oxazol with the diisopropoxythiophosphorylthio group in a side chain, and hydrazone of this aldehyde and diphenylphosphinylacetic acid hydrazide.