ChemInform Abstract: Trapping of Carbolithiation‐Derived Tertiary Benzylic α‐Lithio Piperidines with Carbon Electrophiles: Controlling the Formation of α‐Amino Quaternary and Vicinal Stereocenters. Issue 50 (December 2015)

Record Type:
Journal Article
Title:
ChemInform Abstract: Trapping of Carbolithiation‐Derived Tertiary Benzylic α‐Lithio Piperidines with Carbon Electrophiles: Controlling the Formation of α‐Amino Quaternary and Vicinal Stereocenters. Issue 50 (December 2015)
Main Title:
ChemInform Abstract: Trapping of Carbolithiation‐Derived Tertiary Benzylic α‐Lithio Piperidines with Carbon Electrophiles: Controlling the Formation of α‐Amino Quaternary and Vicinal Stereocenters.
Authors:
Beng, Timothy K.
Fox, Nathan
Bassler, Daniel P.
Alwali, Amir
Sincavage, Kayla
Silaire, Ann Wens V.
Abstract:
Abstract: The carbolithiation of 2‐aryl N‐Boc‐piperidines (I) followed by quenching with MeOH gives rise to 3‐alkylated trans‐products with high diastereoselectivity.
Is Part Of:
ChemInform. Volume 46:Issue 50(2015)
Journal:
ChemInform
Issue:
Volume 46:Issue 50(2015)
Issue Display:
Volume 46, Issue 50 (2015)
Year:
2015
Volume:
46
Issue:
50
Issue Sort Value:
2015-0046-0050-0000
Page Start:
no
Page End:
no
Publication Date:
2015-12
Subjects:
pyridine derivatives -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- C‐C bond formation -- reactions of organo‐metal compounds
Chemistry -- Abstracts -- Periodicals
540.5
Journal URLs:
http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1522-2667 ↗
http://onlinelibrary.wiley.com/ ↗
DOI:
10.1002/chin.201550150 ↗
Languages:
English
ISSNs:
0931-7597
Deposit Type:
Legaldeposit
View Content:
Available online (eLD content is only available in our Reading Rooms) ↗
Physical Locations:
British Library DSC - 3158.195000
British Library DSC - BLDSS-3PM
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Ingest File:
265.xml