ChemInform Abstract: Direct Access to N‐Alkylsulfoximines from Sulfides by a Sequential Imidation/Oxidation Procedure. Issue 49 (December 2015)

• Record Type: Journal Article
• Authors: Dannenberg, Carl Albert; Bizet, Vincent; Bolm, Carsten
• Is Part Of: ChemInform. Volume 46:Issue 49(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-12
• Subjects: thio compounds (benzene compounds) -- aldehyde derivatives (acyclic compounds) -- oxidation, dehydrogenation; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201549071
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The imidating agents N‐bromoalkylamines, generated in situ from methyl amines (II) and bromine, react with sulfides [e.g. (I)] to form sulfiliminium, which was subsequently oxidized to sulfoximines [e.g. (III)] in a short time.