Acylsilanes in Iridium‐Catalyzed Directed Amidation Reactions and Formation of Heterocycles via Siloxycarbenes. (5th November 2015)
- Record Type:
- Journal Article
- Title:
- Acylsilanes in Iridium‐Catalyzed Directed Amidation Reactions and Formation of Heterocycles via Siloxycarbenes. (5th November 2015)
- Main Title:
- Acylsilanes in Iridium‐Catalyzed Directed Amidation Reactions and Formation of Heterocycles via Siloxycarbenes
- Authors:
- Becker, Peter
Pirwerdjan, Ramona
Bolm, Carsten - Abstract:
- Abstract: Exposing ortho‐amido aroylsilanes to visible light or heat leads to cyclization reactions that provide N‐heterocyclic compounds via siloxycarbenes as key intermediates. The previously unreported starting materials have been prepared by directed amidations of aromatic acylsilanes in the presence of an iridium catalyst followed by N‐alkylation.
- Is Part Of:
- Angewandte Chemie. Volume 127:Number 51(2015)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 127:Number 51(2015)
- Issue Display:
- Volume 127, Issue 51 (2015)
- Year:
- 2015
- Volume:
- 127
- Issue:
- 51
- Issue Sort Value:
- 2015-0127-0051-0000
- Page Start:
- 15713
- Page End:
- 15716
- Publication Date:
- 2015-11-05
- Subjects:
- Acylsilane -- Carbene -- C‐H‐Funktionalisierung -- Heterocyclenchemie -- Iridium‐Katalyse
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201508501 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 2320.xml