Extending the Family of V4+S=${{ 1/2 }}$ Kagome Antiferromagnets. (30th October 2015)

• Record Type: Journal Article
• Authors: Clark, Lucy; Aidoudi, Farida H.; Black, Cameron; Arachchige, Kasun S. A.; Slawin, Alexandra M. Z.; Morris, Russell E.; Lightfoot, Philip
• Is Part Of: Angewandte Chemie. Volume 127:Number 51(2015)
• Page Start: 15677
• Page End: 15681
• Publication Date: 2015-10-30
• Subjects: Fluoride -- Kristallwachstum -- Magnetische Eigenschaften -- Röntgenbeugung -- Vanadium; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201506869
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: The ionothermal synthesis, structure, and magnetic susceptibility of a novel inorganic–organic hybrid material, imidazolium vanadium(III, IV) oxyfluoride [C3 H5 N2 ][V9 O6 F24 (H2 O)2 ] (ImVOF) are presented. The structure consists of inorganic vanadium oxyfluoride slabs with kagome layers of V 4+ S =${{ 1/2 }}$ ions separated by a mixed valence layer. These inorganic slabs are intercalated with imidazolium cations. Quinuclidinium (Q) and pyrazinium (Pyz) cations can also be incorporated into the hybrid structure type to give QVOF and PyzVOF analogues, respectively. The highly frustrated topology of the inorganic slabs, along with the quantum nature of the magnetism associated with V 4+, means that these materials are excellent candidates to host exotic magnetic ground states, such as the highly sought quantum spin liquid. Magnetic susceptibility measurements of all samples suggest an absence of conventional long‐range magnetic order down to 2 K despite considerable antiferromagnetic exchange.