Mesostructured Composite Materials with Electrically Tunable Upconverting Properties. Issue 41 (31st August 2015)

• Record Type: Journal Article
• Authors: Mundoor, Haridas; Smalyukh, Ivan I.
• Is Part Of: Small. Volume 11:Issue 41(2015)
• Page Start: 5572
• Page End: 5580
• Publication Date: 2015-08-31
• Subjects: electric switching -- liquid crystals -- orientational order -- polarized luminescence -- upconversion, nanoparticles; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201501788
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract : A promising approach of designing mesostructured materials with novel physical behavior is to combine unique optical and electronic properties of solid nanoparticles with long‐range ordering and facile response of soft matter to weak external stimuli. Here, orientationally ordered nematic liquid crystalline dispersions of rod‐like upconversion nanoparticles are designed, practically realized, and characterized. Boundary conditions on particle surfaces, defined through surface functionalization, promote spontaneous unidirectional self‐alignment of the dispersed rod‐like nanoparticles, mechanically coupled to the molecular ordering direction of the thermotropic nematic liquid crystal host. As host is electrically switched at low voltages ≈1 V, nanorods rotate, yielding tunable upconversion and polarized luminescence properties of the composite. Spectral and polarization dependencies are characterized and explained through invoking models of electrical switching of liquid crystals and upconversion dependence on crystalline matrices of nanorods, and their potential practical uses are discussed. Abstract : Nematic dispersions of upconverting nanorods with orientations mechanically coupled to the molecular ordering direction are realized. As the nematic host is electrically switched at ≈1 V, nanorods rotate to follow it, yielding tunable upconversion and polarized luminescence properties. This is explained through models of liquid crystal switching and upconversion dependence on nanorod matrices.