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ChemInform Abstract: Copper(II)‐Catalyzed Oxidative [3 + 2] Cycloaddition Reactions of Secondary Amines with α‐Diazo Compounds: A Facile and Efficient Synthesis of 1, 2, 3‐Triazoles. Issue 46 (November 2015)
Record Type:
Journal Article
Title:
ChemInform Abstract: Copper(II)‐Catalyzed Oxidative [3 + 2] Cycloaddition Reactions of Secondary Amines with α‐Diazo Compounds: A Facile and Efficient Synthesis of 1, 2, 3‐Triazoles. Issue 46 (November 2015)
Main Title:
ChemInform Abstract: Copper(II)‐Catalyzed Oxidative [3 + 2] Cycloaddition Reactions of Secondary Amines with α‐Diazo Compounds: A Facile and Efficient Synthesis of 1, 2, 3‐Triazoles.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The title reaction of secondary amines with α‐diazo compounds proceeds via a cross‐dehydrogenative coupling process involving a sequential aerobic oxidation/[3+2] cycloaddition/oxidative aromatization procedure and provides an efficient method for the construction of 1, 2, 3‐triazoles in a single step in an atom‐economic manner from readily available starting materials under very mild conditions.</p> </abstract>