Corrosion performance of 3%Cr steel in CO2‐H2S environment compared with carbon steel. Issue 11 (13th March 2015)

• Record Type: Journal Article
• Authors: Liu, W.; Lu, S.‐L.; Zhang, Y.; Fang, Z.‐C.; Wang, X.‐M.; Lu, M.‐X.
• Is Part Of: Materials and corrosion. Volume 66:Issue 11(2015:Nov.)
• Page Start: 1232
• Page End: 1244
• Publication Date: 2015-03-13
• Subjects: Materials -- Periodicals; Metals -- Periodicals; Corrosion and anti-corrosives -- Periodicals; 620.1122305
• DOI: 10.1002/maco.201408174
• Languages: English
• ISSNs: 0947-5117

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <sec id="maco201408174-sec-0001" sec-type="section"> <p>Corrosion behavior of 3wt.% Cr low alloy steel in aqueous CO₂‐H₂S environment was investigated in comparison with API X60 carbon steel using high temperature and high pressure autoclave. The corrosion performance of 3Cr steel was analyzed by XRD, XPS, SEM, EDS and EIS. In CO₂‐H₂S environment, the corrosion scale of 3Cr steel possessed a triple structure of the outer layer of FeS, the middle layer of FeCO₃ and the inner layer of FeCO₃, Cr(OH)₃ and Cr₂O₃. FeS mainly formed through the dissolution and re‐deposition from FeCO₃. Hydrolytic action of Cr³⁺ during corrosion affected the formation process of corrosion scale of 3Cr steel. The Cr‐rich layer of the corrosion scale of 3Cr steel blocked the ions transport through corrosion scale to improve corrosion resistance of 3Cr steel. For H₂S‐containg CO₂ environment, 3Cr steel still exhibited higher corrosion resistance than X60 carbon steel and would be a promising material option in such environment.</p> </sec> </abstract>