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ChemInform Abstract: Selectfluor‐Mediated Simultaneous Cleavage of C—O and C—C Bonds in α, β‐Epoxy Ketones under Transition‐Metal‐Free Conditions: A Route to 1, 2‐Diketones. Issue 45 (November 2015)
Record Type:
Journal Article
Title:
ChemInform Abstract: Selectfluor‐Mediated Simultaneous Cleavage of C—O and C—C Bonds in α, β‐Epoxy Ketones under Transition‐Metal‐Free Conditions: A Route to 1, 2‐Diketones. Issue 45 (November 2015)
Main Title:
ChemInform Abstract: Selectfluor‐Mediated Simultaneous Cleavage of C—O and C—C Bonds in α, β‐Epoxy Ketones under Transition‐Metal‐Free Conditions: A Route to 1, 2‐Diketones.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A transition‐metal‐free, Selectfluor‐mediated reaction of aroyloxiranes gives 1, 2‐diketones in moderate to good yields under oxidative conditions involving a ring‐opening/benzoyl rearrangement/C—C cleavage sequence.</p> </abstract>