<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Various amine derivatives are obtained by vicinal functionalization of N‐alkoxyenamines, derived in situ from aldehydes and isoxazolidine, with the formation of two new carbon‐carbon bonds using an organo‐aluminum reagent and subsequent allyl‐magnesium bromide or tributyltin cyanide as external carbon‐centered nucleophiles.</p> </abstract>