A cascade approach to hetero-pentanuclear manganese-oxide clusters in polyoxometalates and their single-molecule magnet properties1. Issue 32 (28th August 2015)

• Record Type: Journal Article
• Authors: Suzuki, Kosuke; Sato, Rinta; Minato, Takuo; Shinoe, Masahiro; Yamaguchi, Kazuya; Mizuno, Noritaka
• Is Part Of: Dalton transactions. Volume 44:Issue 32(2015)
• Page Start: 14220
• Page End: 14226
• Publication Date: 2015-08-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01363a
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2rw7862m" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Hetero-pentanuclear clusters {MMn₄} with large uniaxial magnetic anisotropy and SMM behavior were successfully synthesized by sequential introduction of metal cations into the trivacant lacunary polyoxometalates.</p> </abstract>