Tailoring the selectivity in 2-butene conversion over supported d0 group 4, 5 and 6 metal hydrides: from dimerization to metathesis1. Issue 10 (21st October 2015)

• Record Type: Journal Article
• Authors: Szeto, Kai C.; Merle, Nicolas; Rios, Cesar; Rouge, Pascal; Castelbou, Jessica Llop; Taoufik, Mostafa
• Is Part Of: Catalysis science & technology. Volume 5:Issue 10(2015:Oct.)
• Page Start: 4765
• Page End: 4771
• Publication Date: 2015-10-21
• Subjects: Catalysis -- Periodicals; 541.395
• DOI: 10.1039/c5cy00582e
• Languages: English
• ISSNs: 2044-4753

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2xvqm6qp" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />2-Butenes are transformed in a continuous flow reactor over metal hydrides of zirconium, tantalum and tungsten supported on silica–alumina. Exceptionally high selectivity to dimeric products is obtained over supported zirconium hydride catalysts.</p> </abstract>