Different mechanisms at different temperatures for the ring-opening polymerization of lactide catalyzed by binuclear magnesium and zinc alkoxides1. Issue 37 (7th October 2015)

• Record Type: Journal Article
• Authors: Sun, Yangyang; Cui, Yaqin; Xiong, Jiao; Dai, Zhongran; Tang, Ning; Wu, Jincai
• Is Part Of: Dalton transactions. Volume 44:Issue 37(2015)
• Page Start: 16383
• Page End: 16391
• Publication Date: 2015-10-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01784j
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2qrnr2q4" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Two binuclear magnesium and zinc alkoxides supported by a bis-salalen type dinucleating heptadentate Schiff base ligand can catalyze the ring-opening polymerization of lactide <italic>via</italic> different mechanisms at different temperatures.</p> </abstract>