Reactivity of a dihydroboron species: synthesis of a hydroborenium complex and an expedient entry into stable thioxo- and selenoxo-boranes1. Issue 36 (28th September 2015)

• Record Type: Journal Article
• Authors: Jaiswal, Kuldeep; Prashanth, Billa; Ravi, Satyam; Shamasundar, K. R.; Singh, Sanjay
• Is Part Of: Dalton transactions. Volume 44:Issue 36(2015)
• Page Start: 15779
• Page End: 15785
• Publication Date: 2015-09-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt02788h
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2qrn9gq2" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Oxidative insertion of sulfur or selenium into the B–H bonds, of bis(phosphinimino)amide stabilized dihydroboron species, followed by H₂S or H₂Se evolution leads to a facile access to stable thioxo- and selenoxo-boranes.</p> </abstract>