Development and Validation of an Analytical Model for Predicting Chronoamperometric Responses of Random Arrays of Micro‐ and Nanodisk Electrodes. Issue 9 (21st July 2015)

• Record Type: Journal Article
• Authors: Sliusarenko, Oleksii; Oleinick, Alexander; Svir, Irina; Amatore, Christian
• Is Part Of: ChemElectroChem. Volume 2:Issue 9(2015)
• Page Start: 1279
• Page End: 1291
• Publication Date: 2015-07-21
• Subjects: Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.201500222
• Languages: English
• ISSNs: 2196-0216

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Quantitative theoretical investigations based on a 3D Brownian motion approach established that our previous "cylindrical" approximation remains valid even for drastically irregular arrays. This result led us to propose a simple analytical equation that can be used to predict the chronoamperometric behavior of such commonly used irregular arrays, taking into account the statistical distributions of the Voronoi cells built around the disk electrodes.</p> </abstract>