In Situ Trapped and Immobilized Palladium Nanoparticles as Active and Clean Catalysts for Suzuki–Miyaura Reaction. Issue 13 (15th September 2015)

• Record Type: Journal Article
• Authors: Li, Yan; Mao, Fei; Chen, Ting; Zhou, Zhicheng; Wang, Yong; Huang, Jun
• Is Part Of: Advanced synthesis & catalysis. Volume 357:Issue 13(2015)
• Page Start: 2827
• Page End: 2832
• Publication Date: 2015-09-15
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201500460
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Active palladium nanoparticles were trapped and immobilized <italic>in situ</italic> by Pd‐catalyzed Suzuki–Miyaura reaction to form heterogeneous Pd catalysts. This Pd@PhPad₂ catalyst was found to be highly active, recyclable and clean for the Suzuki–Miyaura reaction. Both the anchored diadamantylphosphine ligand and the formation of polyphenylene polymer improved the activity and stability of the Pd@PhPad₂ catalyst for Suzuki–Miyaura reaction. The Pd@PhPad₂ catalyst was reusable, and no contamination (P ligand or Pd) was detected from the catalyst system for the coupling reaction.</p> <p> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgj2n0t4np2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </p> </abstract>