<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Various 2‐aminophenols and 2‐bromofluorobenzenes are used as substrates for the convenient one‐pot synthesis of a wide range of dibenzoxazepinones by a palladium‐catalyzed aminocarbonylation/aromatic nucleophilic substitution sequence.</p> </abstract>