Pentanuclear lanthanide pyramids based on thiacalix[4]arene ligand exhibiting slow magnetic relaxation1. Issue 35 (21st September 2015)

• Record Type: Journal Article
• Authors: Ge, Jing-Yuan; Ru, Jing; Gao, Feng; Song, You; Zhou, Xin-Hui; Zuo, Jing-Lin
• Is Part Of: Dalton transactions. Volume 44:Issue 35(2015)
• Page Start: 15481
• Page End: 15490
• Publication Date: 2015-09-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt02062j
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2gzgm987" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Six pentanuclear Ln^III clusters have been isolated based on thiacalix[4]arene ligand for the first time. Two Dy₅ clusters feature distinct slow magnetic relaxation, which is affected presumably by the ligand, field molecular symmetry and coordination geometries of lanthanide ions.</p> </abstract>