A hydrothermally stable Zn(ii)-based metal–organic framework: structural modulation and gas adsorption1. Issue 35 (21st September 2015)

• Record Type: Journal Article
• Authors: Zhang, Xiuling; Zhang, Yong-Zheng; Zhang, Da-Shuai; Zhu, Baoyong; Li, Jian-Rong
• Is Part Of: Dalton transactions. Volume 44:Issue 35(2015)
• Page Start: 15697
• Page End: 15702
• Publication Date: 2015-09-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01770j
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2gzgmn7v" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A hydrothermally stable MOF, [Zn₂(tcpt)OH]·solvents (<bold>1</bold>·solvents), was synthesized, in which an unusual paddlewheel SBU, Zn₂(COO)₃, was found. Furthermore, <bold>1</bold> can adsorb considerable amounts of H₂ and displays high selective adsorption of CO₂ over N₂.</p> </abstract>