Copper(i)-photocatalyzed trifluoromethylation of alkenes1. Issue 46 (11th June 2015)

• Record Type: Journal Article
• Authors: Beniazza, R.; Molton, F.; Duboc, C.; Tron, A.; McClenaghan, N. D.; Lastécouères, D.; Vincent, J.-M.
• Is Part Of: Chemical communications. Volume 51:Issue 46(2015)
• Page Start: 9571
• Page End: 9574
• Publication Date: 2015-06-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc01923k
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjqwgshcr" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Using the photoreducible Cu^II precatalyst <bold>2</bold>, trifluoromethylation of terminal alkenes can be conducted at low copper loading on exposing the reaction mixture to sunlight/ambient light.</p> </abstract>