A Gallium‐Substituted Distibene and an Antimony‐Analogue Bicyclo[1.1.0]butane: Synthesis and Solid‐State Structures. Issue 36 (6th August 2015)

• Record Type: Journal Article
• Authors: Tuscher, Lars; Ganesamoorthy, Chelladurai; Bläser, Dieter; Wölper, Christoph; Schulz, Stephan
• Is Part Of: Angewandte Chemie international edition. Volume 54:Issue 36(2015)
• Page Start: 10657
• Page End: 10661
• Publication Date: 2015-08-06
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201502827
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>RGa {R=HC[C(Me)N(2, 6‐<italic>i</italic>Pr₂C₆H₃)]₂} reacts with Sb(NMe₂)₃ with insertion into the SbN bond and elimination of RGa(NMe₂)₂ (<bold>2</bold>), yielding the Ga‐substituted distibene R(Me₂N)GaSbSbGa(NMe₂)R (<bold>1</bold>). Thermolysis of <bold>1</bold> proceeded with elimination of RGa and <bold>2</bold> and subsequent formation of the bicyclo[1.1.0]butane analogue [R(Me₂N)Ga]₂Sb₄ (<bold>3</bold>).</p> </abstract>