Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes1. Issue 34 (14th September 2015)

• Record Type: Journal Article
• Authors: Wu. M, Melissa; Gill, Arran M.; Yunpeng, Lu; Falivene, Laura; Yongxin, Li; Ganguly, Rakesh; Cavallo, Luigi; García, Felipe
• Is Part Of: Dalton transactions. Volume 44:Issue 34(2015)
• Page Start: 15166
• Page End: 15174
• Publication Date: 2015-09-14
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00079c
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2g316v04" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Treatment of a series of aromatic NHCs with trimethylaluminium produced their corresponding NHC·AlMe₃ adducts displaying different stabilities. Their stabilities are rationalized using topographic steric maps and NHC % V Bur.</p> </abstract>