Facile redox state manipulation in Cu(i) frameworks by utilisation of the redox-active tris(4-(pyridin-4-yl)phenyl)amine ligand1. Issue 34 (14th September 2015)

• Record Type: Journal Article
• Authors: Hua, Carol; Turner, Peter; D'Alessandro, Deanna M.
• Is Part Of: Dalton transactions. Volume 44:Issue 34(2015)
• Page Start: 15297
• Page End: 15303
• Publication Date: 2015-09-14
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01233c
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2g316z60" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Two Cu(<sc>i</sc>) frameworks were synthesised with the NPy₃ ligand and Cu(<sc>ii</sc>) salts to yield electroactive Cu(<sc>i</sc>) frameworks whose spectral properties varied as a function of the redox state.</p> </abstract>