The stereoselective formation of highly substituted CF3-dihydropyrans as versatile building blocks1. Issue 71 (14th September 2015)

• Record Type: Journal Article
• Authors: Donslund, Bjarke S.; Monleón, Alicia; Larsen, Jesper; Ibsen, Lise; Jørgensen, Karl Anker
• Is Part Of: Chemical communications. Volume 51:Issue 71(2015)
• Page Start: 13666
• Page End: 13669
• Publication Date: 2015-09-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc04874e
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2g30dfs2" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The dienamine-mediated formal inverse electron demand hetero Diels–Alder reaction providing optically active 5-bromo-6-(trifluoromethyl)-3, 4-dihydro-<italic>2H</italic>-pyrans is disclosed along with interesting transformations, affording a large variety of fully substituted dihydropyrans.</p> </abstract>