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A DFT study of the role of the Lewis acid catalysts in the [3 + 2] cycloaddition reaction of the electrophilic nitrone isomer of methyl glyoxylate oxime with nucleophilic cyclopentene1. Issue 79 (28th August 2015)
Record Type:
Journal Article
Title:
A DFT study of the role of the Lewis acid catalysts in the [3 + 2] cycloaddition reaction of the electrophilic nitrone isomer of methyl glyoxylate oxime with nucleophilic cyclopentene1. Issue 79 (28th August 2015)
Main Title:
A DFT study of the role of the Lewis acid catalysts in the [3 + 2] cycloaddition reaction of the electrophilic nitrone isomer of methyl glyoxylate oxime with nucleophilic cyclopentene1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2ds82mc9" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The mechanism and stereoselectivity of the BH<sub>3</sub>-catalysed 32CA reaction between <italic>C</italic>-methoxycarbonyl nitrone and cyclopentene has been studied using MPWB1K/6-31G(d) computational level.</p> </abstract>