Complexation of uranium(vi) with glutarimidoxioxime: thermodynamic and computational studies1. Issue 31 (21st August 2015)

• Record Type: Journal Article
• Authors: Endrizzi, Francesco; Melchior, Andrea; Tolazzi, Marilena; Rao, Linfeng
• Is Part Of: Dalton transactions. Volume 44:Issue 31(2015)
• Page Start: 13835
• Page End: 13844
• Publication Date: 2015-08-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00261c
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2df4w1hc" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Glutarimidoxioxime forms a bidentate complex with UO₂²⁺<italic>via</italic> the oxime and imino groups. Hydrogen bonding between water and the carbonyl group helps to stabilize the complex. The complex is much weaker than that of glutarimidedioxime previously studied.</p> </abstract>