Characterization of a Rh(iii) porphyrin–CO complex: its structure and reactivity with an electron acceptor1. Issue 31 (21st August 2015)

• Record Type: Journal Article
• Authors: Yamazaki, Shin-ichi; Yao, Masaru; Asahi, Masafumi; Sato, Hiroyasu; Yamano, Akihito; Ioroi, Tsutomu
• Is Part Of: Dalton transactions. Volume 44:Issue 31(2015)
• Page Start: 13823
• Page End: 13827
• Publication Date: 2015-08-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01453k
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2df4wcp9" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />To analyse the electrocatalytic oxidation of carbon monoxide by Rh porphyrins, we isolated a CO-adduct of Rh octaethylporphyrin, and examined its properties and reactivity by IR, NMR, and X-ray crystallographic analyses.</p> </abstract>