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Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes1. Issue 65 (21st August 2015)
Record Type:
Journal Article
Title:
Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes1. Issue 65 (21st August 2015)
Main Title:
Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2df3g4ks" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Title transformation has been disclosed wherein CO<sub>2</sub> is chemoselectively reduced to the alcohol oxidation level to provide homoallylic alcohols, with esters or other reducible functionalities on the allenes being intact.</p> </abstract>