Carbene: Solvent‐Induced Facile Synthesis of Cubic‐, Spherical‐, and Honeycomb‐Shape Palladium N‐Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation (Small 30/2015). Issue 30 (August 2015)

• Record Type: Journal Article
• Authors: Zhao, Huaixia; Li, Xinxiong; Li, Liuyi; Wang, Ruihu
• Is Part Of: Small. Volume 11:Issue 30(2015)
• Page Start: 3641
• Page End: 3641
• Publication Date: 2015-08
• Subjects: Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201570180
• Languages: English
• ISSNs: 1613-6810

Abstract

<abstract abstract-type="graphical" xml:lang="en" id="smll201570180-abs-0001"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The facile synthesis of palladium N‐heterocyclic carbene (NHC) particles with spherical, cubic, and honeycomb morphologies is accomplished by R. Wang and co‐workers through adjusting solvent polarity. The structures of the cubic and honeycomb particles are defined as an unprecedented trinuclear palladium‐NHC complex. On page 3642, the relationship between the crystal structures and organometallic particles is established. An obvious effect of particle morphologies on catalytic activity and recyclability is observed in heterogeneous cyanosilylation. <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgj2cr1rsz0" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></p> </abstract>