Influence of the Different Dicarboxylate Ligands on The Topological Net of Manganese(II) Coordination Polymers: Syntheses, Crystal Structures. and Luminescent Properties1. Issue 10 (1st June 2015)

• Record Type: Journal Article
• Authors: Deng, Xiaoqi
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 641:Issue 10(2015)
• Page Start: 1701
• Page End: 1705
• Publication Date: 2015-06-01
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201500207
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The self‐assembly of Mn^II ions and 1, 4‐bis(2‐methyl‐imidazole‐1‐yl)benzene (bip) with two different dicarboxylate ligands, benzophenone‐4, 4′‐dicarboxylic acid (H₂bda) and 1, 4‐naphthalenedicarboxylic acid (H₂nda) via hydrothermal synthesis resulted in two interesting coordination polymers, [Mn(bda)(bip)]<italic>_n</italic> (<bold>1</bold>) and [(Mn(nda)(bip)_0.5(H₂O)]<italic>_n</italic> (<bold>2</bold>). Their structures were determined by single‐crystal X‐ray diffraction and elemental analyses, as well as IR spectroscopy. Complex <bold>1</bold> exhibits an unusual polycatenated 2D+2D→3D framework. Complex <bold>2</bold> shows a twofold interpenetrated pcu net. In addition, the solid‐state photoluminescent properties of <bold>1</bold> and <bold>2</bold> were investigated at room temperature.</p> </abstract>