A 3D Polyoxometalate‐Based Framework Constructed from Ag/trz Metal‐Organic Ribbons and P2W18 Polyoxoanions: Synthesis, Structure and Electrochemical Properties1. Issue 10 (3rd June 2015)

• Record Type: Journal Article
• Authors: Wang, Xiang; Zhang, Rui; Tian, Aixiang; Wang, Xiuli
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 641:Issue 10(2015)
• Page Start: 1718
• Page End: 1721
• Publication Date: 2015-06-03
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201500216
• Languages: English
• ISSNs: 0044-2313

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A Wells‐Dawson Polyoxometalate‐based hybrid, Ag₉(trz)₃(Htrz)₄ (H₂O)(P₂W₁₈O₆₂)·3H₂O (<bold>1</bold>) (Htrz = 1, 2, 4‐1H‐triazole) was hydrothermally synthesized through using trz ligand and silver nitrate in the presence of [P₂W₁₈O₆₂]^6– polyoxoanion. In the 3D framework structure of compound <bold>1</bold>, two kinds of wave‐like Ag/trz chains originated from trz ligands and silver cations are aggregated in a "2+1" mode by {Ag₂/trz} linkages to result in a 1D Ag/trz metal‐organic ribbon, which is further extended into a 3D framework structure by [P₂W₁₈O₆₂]^6– polyoxoanions through Ag‐O covalent bonds. Additionally, the electrochemical properties of compound <bold>1</bold> have also been investigated.</p> </abstract>