A Triazolyl‐Pyridine‐Supported CuI Dimer: Tunable Luminescence and Fabrication of Composite Fibers. Issue 8 (6th July 2015)

• Record Type: Journal Article
• Authors: Bai, Shi‐Qiang; Kai, Dan; Ke, Karen Lin; Lin, Ming; Jiang, Lu; Jiang, Ying; Young, David James; Loh, Xian Jun; Li, Xu; Hor, T. S. Andy
• Is Part Of: ChemPlusChem. Volume 80:Issue 8(2015:Aug.)
• Page Start: 1235
• Page End: 1240
• Publication Date: 2015-07-06
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cplu.201500202
• Languages: English
• ISSNs: 2192-6506

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The dinuclear complex [Cu₂I₂(L1)₂] (<bold>1</bold>) (L1=3‐((4‐(pyridin‐2‐yl)‐1<italic>H</italic>‐1, 2, 3‐triazol‐1‐yl)methyl)benzonitrile) is characterized by single‐crystal X‐ray diffraction (XRD), powder XRD, IR, photoluminescence spectroscopy, and thermogravimetric analysis. Unlike other related, known copper iodide complexes, it exhibits strong yellow emission in the solid state at both room temperature and 77 K. Showing good compatibility with PMMA, it is blended with the polymer in different weight ratios to prepare luminescent composite fibers.</p> </abstract>