Facile synthesis of 1-trifluoromethylalkenes via the decarboxylation of α-trifluoromethyl-β-lactones1. Issue 62 (11th August 2015)
- Record Type:
- Journal Article
- Title:
- Facile synthesis of 1-trifluoromethylalkenes via the decarboxylation of α-trifluoromethyl-β-lactones1. Issue 62 (11th August 2015)
- Main Title:
- Facile synthesis of 1-trifluoromethylalkenes via the decarboxylation of α-trifluoromethyl-β-lactones1
- Authors:
- Veeraraghavan Ramachandran, P.
Otoo, Barnabas - Abstract:
- <abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2b31nzzw" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />DCC-mediated cyclodehydration of α-trifluoromethyl-β-hydroxy acids provides α-trifluoromethylated β-lactone intermediates, without loss of stereoselectivity. These lactones undergo facile decarboxylation providing a simple route to obtain both alkyl and aryl 1-trifluoromethyl alkenes in excellent yields and stereoselectivity.</p> </abstract>
- Is Part Of:
- Chemical communications. Volume 51:Issue 62(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 62(2015)
- Issue Display:
- Volume 51, Issue 62 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 62
- Issue Sort Value:
- 2015-0051-0062-0000
- Page Start:
- 12388
- Page End:
- 12390
- Publication Date:
- 2015-08-11
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc03230j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3448.xml