A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide1. Issue 64 (18th August 2015)
- Record Type:
- Journal Article
- Title:
- A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide1. Issue 64 (18th August 2015)
- Main Title:
- A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide1
- Authors:
- Son, Jung-Ho
Casey, William H. - Abstract:
- <abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2b2vrz1s" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Solid niobium phosphate (NbOPO<sub>4</sub>·<italic>x</italic>H<sub>2</sub>O) is well known as a biomass-conversion catalyst, yet the chemical pathways are unclear. Here we report solution chemistry of a new niobophosphate cluster [H<sub>3</sub>Nb<sub>9</sub>P<sub>5</sub>O<sub>41</sub>]<sup>9−</sup> that reacts with H<sub>2</sub>O<sub>2</sub> to form peroxo-Nb<sub>4</sub>P<sub>2</sub>, and this reaction can be reversed by hydrothermal treatment. We suggest that this cluster is a useful molecular model for the solid.</p> </abstract>
- Is Part Of:
- Chemical communications. Volume 51:Issue 64(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 64(2015)
- Issue Display:
- Volume 51, Issue 64 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 64
- Issue Sort Value:
- 2015-0051-0064-0000
- Page Start:
- 12744
- Page End:
- 12747
- Publication Date:
- 2015-08-18
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc03782d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4322.xml