A dinaphtho[8, 1, 2-cde:2′, 1′, 8′-uva]pentacene derivative and analogues: synthesis, structures, photophysical and electrochemical properties1. Issue 28 (28th July 2015)

• Record Type: Journal Article
• Authors: Li, Xiao-Jun; Li, Meng; Lu, Hai-Yan; Chen, Chuan-Feng
• Is Part Of: Organic & biomolecular chemistry. Volume 13:Issue 28(2015)
• Page Start: 7628
• Page End: 7632
• Publication Date: 2015-07-28
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c5ob01008j
• Languages: English
• ISSNs: 1477-0520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj26bckhs9" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Dinaphtho[8, 1, 2-<italic>cde</italic>:2′, 1′, 8′-<italic>uva</italic>]pentacene with a scorpion-shaped structure has a twisted configuration, but shows marked intermolecular π–π interactions, strong electronic delocalization, and a small HOMO–LUMO bandgap.</p> </abstract>