Ternary transition-metal fluoride precursors for the fluorolytic sol–gel route: new insights into speciation and decomposition1. Issue 29 (7th August 2015)

• Record Type: Journal Article
• Authors: Kohl, J.; Wiedemann, D.; Troyanov, S. I.; Palamidis, E.; Lerch, M.
• Is Part Of: Dalton transactions. Volume 44:Issue 29(2015)
• Page Start: 13272
• Page End: 13281
• Publication Date: 2015-08-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01748c
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj268dhstn" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />After successive, incomplete fluorination, complexes containing the motifs [MF_{<italic>n</italic>}]^{(3−<italic>n</italic>)+} (M = V, Mn, Ni; <italic>n</italic> = 0–4) have been trapped with pyridine and identified using X-ray diffraction.</p> </abstract>