Nanometer-scale separation of d10 Zn2+-layers and twin–shift competition in Ba8ZnNb6O24-based 8-layered hexagonal perovskites1. Issue 29 (7th August 2015)

• Record Type: Journal Article
• Authors: Lu, Fengqi; Wang, Xiaoming; Pan, Zhengwei; Pan, Fengjuan; Chai, Shiqiang; Liang, Chaolun; Wang, Quanchao; Wang, Jing; Fang, Liang; Kuang, Xiaojun; Jing, Xiping
• Is Part Of: Dalton transactions. Volume 44:Issue 29(2015)
• Page Start: 13173
• Page End: 13185
• Publication Date: 2015-08-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00859j
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj268dj3ht" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The shifted hexagonal perovskite Ba₈ZnNb₆O₂₄ demonstrates ∼ 1.9 nm separation of octahedral d¹⁰ Zn²⁺-layers and twin–shift competition upon Sb⁵⁺/Ta⁵⁺ substitution for Nb⁵⁺.</p> </abstract>