Synthesis and characterization of novel niccolites [(CH3)2NH2][FeIIIMII(HCOO)6] (MII = Zn, Ni, Cu)1. Issue 29 (7th August 2015)

• Record Type: Journal Article
• Authors: Ciupa, Aneta; Mączka, Mirosław; Gągor, Anna; Pikul, Adam; Ptak, Maciej
• Is Part Of: Dalton transactions. Volume 44:Issue 29(2015)
• Page Start: 13234
• Page End: 13241
• Publication Date: 2015-08-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01608h
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj268dhm41" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />We report the synthesis, structural, magnetic, Raman and IR studies of novel niccolite-type heterometallic [(CH₃)₂NH₂][Fe^IIIM^II(HCOO)₆] compounds (M^II = Ni, Zn and Cu). The Ni and Cu compounds order ferromagnetically at 42 and 28.5 K, respectively. The monoclinic Cu member exhibits different structural changes on cooling than the trigonal Zn and Ni compounds.</p> </abstract>