Reversing the relative 3MLCT–3MC order in Fe(ii) complexes using cyclometallating ligands: a computational study aiming at luminescent Fe(ii) complexes1. Issue 30 (14th August 2015)

• Record Type: Journal Article
• Authors: Dixon, Isabelle M.; Alary, Fabienne; Boggio-Pasqua, Martial; Heully, Jean-Louis
• Is Part Of: Dalton transactions. Volume 44:Issue 30(2015)
• Page Start: 13498
• Page End: 13503
• Publication Date: 2015-08-14
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01214g
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj26882jrv" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Positioning two cyclometallating rings on the periphery of tridentate ligands has allowed us to design for the first time an iron(<sc>ii</sc>) complex bearing the lowest triplet state of MLCT nature.</p> </abstract>