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A 1, 2, 4-diazaphospholyl radical and its nitrogen–phosphorus coupled dimer: synthesis, X-ray structural characterization, EPR analysis, and computational studies1. Issue 63 (14th August 2015)
Record Type:
Journal Article
Title:
A 1, 2, 4-diazaphospholyl radical and its nitrogen–phosphorus coupled dimer: synthesis, X-ray structural characterization, EPR analysis, and computational studies1. Issue 63 (14th August 2015)
Main Title:
A 1, 2, 4-diazaphospholyl radical and its nitrogen–phosphorus coupled dimer: synthesis, X-ray structural characterization, EPR analysis, and computational studies1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj2684bmn9" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The oxidation of 1, 2, 4-diazaphospholide potassium (K<sup>+</sup>[<bold>2<sup>−</sup></bold>]) produced a neutral 1, 2, 4-diazaphospholyl radical (<bold>2˙</bold>) that was able to self-associate through a N–P coupling to give a <bold>2</bold>(N)–<bold>2</bold>(P) dimer.</p> </abstract>