ChemInform Abstract: Reaction of 1‐Substituted Benzimidazoles with Acylacetylenes and Water: Ring‐Opening versus Ring‐Expansion and Isotopic Effect of Deuterium. Issue 32 (August 2015)

• Record Type: Journal Article
• Authors: Belyaeva, Kseniya V.; Andriyankova, Lyudmila V.; Nikitina, Lina P.; Bagryanskaya, Irina Yu.; Afonin, Andrei V.; Ushakov, Igor A.; Mal'kina, Anastasiya G.; Trofimov, Boris A.
• Is Part Of: ChemInform. Volume 46:Issue 32(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-08
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201532036
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Title compounds (I) react with acylacetylenes (II) and water to give stereoselectively functionalized (Z)‐arylaminovinyl ketones (III), products of imidazole ring‐opening, as main products and benzodiazocinones (IV), products of the imidazole ring‐expansion, as side‐products.</p> </abstract>