Dispersion, solvent and metal effects in the binding of gold cations to alkynyl ligands: implications for Au(i) catalysis1. Issue 47 (14th June 2015)

• Record Type: Journal Article
• Authors: Ciano, Luisa; Fey, Natalie; Halliday, Connor J. V.; Lynam, Jason M.; Milner, Lucy M.; Mistry, Nimesh; Pridmore, Natalie E.; Townsend, Nell S.; Whitwood, Adrian C.
• Is Part Of: Chemical communications. Volume 51:Issue 47(2015)
• Page Start: 9702
• Page End: 9705
• Publication Date: 2015-06-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc02629f
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1zk76xrr" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The ability of gold(<sc>i</sc>) cations to coordinate to alkynyl ligands allows for the formation of di- and trinuclear scaffolds. This reinforces the notion that multiple gold coordination may play a key role in catalysis.</p> </abstract>