Nickel(ii) radical complexes of thiosemicarbazone ligands appended by salicylidene, aminophenol and aminothiophenol moieties1. Issue 28 (28th July 2015)

• Record Type: Journal Article
• Authors: Kochem, Amélie; Gellon, Gisèle; Jarjayes, Olivier; Philouze, Christian; du Moulinet d'Hardemare, Amaury; van Gastel, Maurice; Thomas, Fabrice
• Is Part Of: Dalton transactions. Volume 44:Issue 28(2015)
• Page Start: 12743
• Page End: 12756
• Publication Date: 2015-07-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00944h
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1xv6f3p3" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The neutral nickel(<sc>ii</sc>) complexes are chameleon pro-radical compounds: under their one-electron oxidized form they feature an iminosemiquinonate (or iminothiosemiquinonate) radical, while under their reduced form they are α-diimine π-radicals.</p> </abstract>