Modeling the magnetic properties of lanthanide complexes: relationship of the REC parameters with Pauling electronegativity and coordination number1. Issue 28 (28th July 2015)

• Record Type: Journal Article
• Authors: Baldoví, José J.; Gaita-Ariño, Alejandro; Coronado, Eugenio
• Is Part Of: Dalton transactions. Volume 44:Issue 28(2015)
• Page Start: 12535
• Page End: 12538
• Publication Date: 2015-07-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01839k
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1xv6f5hc" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The REC model has proven to be useful to study lanthanide SIMs. But do its effective charge parameters have any physical meaning? Here we relate <italic>D</italic>_r and <italic>Z</italic>_{<italic>i</italic>} with the coordination numbers, valence and electronegativity.</p> </abstract>